美国队长史蒂夫·罗杰斯(克里斯·埃文斯 Chris Evans 饰)带领着全新组建的复仇者联盟,继续维护世界和平。然而,一次执行任务时联盟成员不小心造成大量平民伤亡,从而激发政治压力,政府决定通过一套监管系统来管理和领导复仇者联盟。联盟内部因此分裂为两派:一方由史蒂夫· 罗杰斯领导,他主张维护成员自由,在免受政府干扰的情况下保护世界;另一方则追随托尼·斯塔克(小罗伯特·唐尼 Robert Downey Jr. 饰),他令人意外地决定支持政府的监管和责任制体系。神秘莫测的巴基(塞巴斯蒂安·斯坦 Sebastian Stan 饰)似乎成为内战的关键人物……
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